Application of new parameterizations of gas transfer velocity and their impact on regional and global marine CO2 budgets

One of the dominant sources of uncertainty in the calculation of air–sea flux of carbon dioxide on a global scale originates from the various parameterizations of the gas transfer velocity, k, that are in use. Whilst it is undisputed that most of these parameterizations have shortcomings and neglect processes which influence air–sea gas exchange and do not scale with wind speed alone, there is no general agreement about their relative accuracy.The most widely used parameterizations are based on non-linear functions of wind speed and, to a lesser extent, on sea surface temperature and salinity. Processes such as surface film damping and whitecapping are known to have an effect on air–sea exchange. More recently published parameterizations use friction velocity, sea surface roughness, and significant wave height. These new parameters can account to some extent for processes such as film damping and whitecapping and could potentially explain the spread of wind-speed based transfer velocities published in the literature.We combine some of the principles of two recently published k parameterizations [Glover, D.M., Frew, N.M., McCue, S.J. and Bock, E.J., 2002. A multiyear time series of global gas transfer velocity from the TOPEX dual frequency, normalized radar backscatter algorithm. In: Donelan, M.A., Drennan, W.M., Saltzman, E.S., and Wanninkhof, R. (Eds.), Gas Transfer at Water Surfaces, Geophys. Monograph 127. AGU,Washington, DC, 325–331; Woolf, D.K., 2005. Parameterization of gas transfer velocities and sea-state dependent wave breaking. Tellus, 57B: 87–94] to calculate k as the sum of a linear function of total mean square slope of the sea surface and a wave breaking parameter. This separates contributions from direct and bubble-mediated gas transfer as suggested by Woolf [Woolf, D.K., 2005. Parameterization of gas transfer velocities and sea-state dependent wave breaking. Tellus, 57B: 87–94] and allows us to quantify contributions from these two processes independently.We then apply our parameterization to a monthly TOPEX altimeter gridded 1.5° × 1.5° data set and compare our results to transfer velocities calculated using the popular wind-based k parameterizations by Wanninkhof [Wanninkhof, R., 1992. Relationship between wind speed and gas exchange over the ocean. J. Geophys. Res., 97: 7373–7382.] and Wanninkhof and McGillis [Wanninkhof, R. and McGillis, W., 1999. A cubic relationship between air−sea CO2 exchange and wind speed. Geophys. Res. Lett., 26(13): 1889–1892]. We show that despite good agreement of the globally averaged transfer velocities, global and regional fluxes differ by up to 100%. These discrepancies are a result of different spatio-temporal distributions of the processes involved in the parameterizations of k, indicating the importance of wave field parameters and a need for further validation.     

Initial results from long-term measurements of atmospheric humidity and related parameters in the marine boundary layer at two locations in the Gulf of Mexico

Measurements of boundary layer moisture have been acquired from Rotronic MP-100 sensors deployed on two NDBC buoys in the northern Gulf of Mexico from June through November 1993. For one sensor, which was retrieved approximately 8 months after deployment, the post- and precalibrations agreed closely and fell well within WMO specifications for accuracy. The second sensor operated continuously from June 1993 to February 1997 (3.5 years). Buoy observations of relative humidity and supporting data were used to calculate specific humidity and the surface fluxes of latent and sensible heat. Specific humidities from the buoys were compared with observations of moisture obtained from nearby ship reports, and the correlations were generally high (0.7–0.9). Surface gravity wave spectra were also acquired. The time series of specific humidity and the other buoy parameters revealed three primary scales of variability, small (h), synoptic (days), and seasonal (months). The synoptic variability was clearly dominant and occurred primarily during September, October, and November. Most of the synoptic variability was due to frontal systems that dropped down into the Gulf of Mexico from the continental US followed by air masses which were cold and dry. Cross-correlation analyses of the buoy data indicated that: (1) the moisture field was highly coherent over distances of 800 km or more in the northern Gulf of Mexico; and (2) both specific humidity and air temperature served as tracers of the motion associated with propagating atmospheric disturbances. These correlation analyses also revealed that the prevailing weather systems generally entered the buoy domain from the South prior to September, but primarily from the North thereafter. Spectra of the various buoy parameters indicated strong diurnal and semidiurnal variability for barometric pressure and sea surface temperature (SST) and lesser variability for air temperature, wind speed and significant wave height. The surface fluxes of latent and sensible heat were dominated by the synoptic events which took place from September through November with the transfer of latent heat being primarily from the ocean to the atmosphere. Finally, an analysis of the surface wave observations from each buoy, which included calculations of wave age and estimates of surface roughness, indicate that major heat and moisture flux events coincide with periods of active wave growth, although the data were insufficient to identify any causal relationships.     

A tool to aid redesign of flexible transport services to increase efficiency in rural transport service provision

Rural areas generally have lower and more dispersed demands for travel which cannot sustain conventional public transport services and consequently have a greater number of flexible and demand responsive transport services operating. These services usually operate on a stand-alone basis, are often subsidized and are typically only accessible by certain passenger types or for specific trip purposes. This generally results in uncoordinated and inefficient transport provision overall. The Flexible integrated transport services (FITS) system featured in this paper has been designed to address this problem. FITS can be used as a planning tool to assess potential benefits from relaxing operating constraints (e.g., a service's operating boundaries), which can potentially suggest service redesign. It also includes the capacity to assign subsidy payments on a trip by trip basis to increase cost efficiency whilst meeting a greater proportion of transport needs. The case study in the paper focusses on transport to health in the Aberdeenshire and Morayshire areas of Scotland in the UK. Despite flexible transport operators receiving public funds to meet passenger needs, this is currently being supplemented by public bodies paying large amounts in taxi fares in instances where there is a statutory obligation to provide travel but where no other suitable transport service exists. The results demonstrate the potential substantial savings which could be realized by allowing transport operators to redesign their services by relaxing constraints and by the reassignment of subsidies: resulting in more passenger demands being met and a reduction in public spending on taxi fares.     

“Local background” levels of carbon monoxide in an urban area

The objective of this study was to obtain a better understanding of carbon monoxide (CO) concentrations immediately upwind of urban roadways, the “local background” values, and how these concentrations depend upon the surrounding traffic and the general meteorology. Measurements were made at seven sites in Seattle, WA during the winter of 1993. Local background CO concentrations were characterized by an absence of short term fluctuations, a steady buildup during the 3 p.m. to 11 p.m. period, and a lack of spatial gradients in the 8-h average values. Distinctly different log-normal distributions of the 8-h averages were observed for “trafficked” sites versus “urban park” sites, with mean values of 1.6 and 1.0 ppm respectively. A simple regression model was developed to predict the local background CO that includes distance from roadway, average daily traffic of nearby roadways, and the frequency of occurrence of low wind speeds (R² = 0.74; F = 170).     

The influence of habit formation on modal choice —a Heuristic model

Most modal split models have been based on the assumption of rational behaviour in an individual's choice evaluation of the generalised costs of modal alternatives. This paper integrates conceptual and empirical information from a wide range of sources and points towards an alternative way of looking at modal choice. The main conclusion is that the car is usually perceived as the superior mode for vehicular travel and that the potential user is committed to its use largely through the act of purchasing it. The conceptual structure of a sequential modal split model is outlined as one that is based on a four-stage decision-making framework which considers the role of learning and habit-formation. In the conclusion, the implications of this approach are considered in terms of the conventional modal split and trip generation submodels, and certain policy measures are assessed.     

The role of information in ocean-shipping management

In this article the nature of information in the ocean shipping industry is analysed and an information system for processing industry data is outlined. The system collects and verifies data from many sources and supplies input for the decision-maker, in a comprehensible format, based on facts and not on estimates. Typical applications of the system are discussed and their impact in several cases is presented.     

Traffic assignment by trip type using volume restraint and link restraint for application in small urban areas

This research involved the development of a new traffic assignment model consisting of a set of procedures for an urbanized area with a population of 172,000. Historical, social, and economic data were used as input to conventional trip generation and trip distribution models to produce a trip table for network assignment. This fixed table was divided into three trip types: external-external trips, external-internal trips, and internal-internal trips. The methodology used to develop the new traffic assignment model assigned each of the trip types by varying the diversion of trips from the minimum path. External-external trips were assigned on a minimum path routing and external-internal trips were assigned with a slight diversion from the minimum path. Internal-internal trips were assigned with more diversion than external-internal trips and adjusted by utilizing iterative volume restraint and incremental link restraint. A statistical analysis indicated that assigning trips by trip types using trip diversion and volume and link restraint produces a significant improvement in the accuracy of the assigned traffic volumes.